Inorganic Chemistry p. 352 - 354 (1979)
Update date:2022-07-29
Topics:
Mahler, Walter
Oxygen reacts with tris(trifluoromethyl)phosphine by a chain reaction involving the trifluoromethyl radical and its autoxidation. With thermal quenching, tris(trifluoromethyl) phosphate and bis(trifluoromethyl)fluorophosphine oxide are formed. Under conditions of spontaneous ignition the latter compound delivers CF2, a powerful reducing agent.
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Doi:10.1021/acs.orglett.1c01716
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(1988)
