Tetrahedron Letters p. 227 - 230 (1992)
Update date:2022-09-26
Topics:
Boitrel, Bernard
Lecas-Nawrocka, Alexandra
Rose, Eric
The new hexadentate bis-strapped porphyrin 6 has been synthesized with two different ansa, bringing in an intramolecular way, a nitrogen base and a thioether sixth ligand both necessary to mimic the natural cytochrome-C protein. 1H NMR spectroscopy indicates clearly the six coordination of the iron atom.Key Words: cytochrome-C/ porphyrin/ modelisation/ six-coordinate Fe(II)
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