Journal of the American Chemical Society p. 1611 - 1618 (1980)
Update date:2022-08-04
Topics:
Creary, Xavier
Singlet carbenes add preferentially to the more substituted bond of 1,1-dimethylallene (1), to give methylenecyclopropanes 3 as the major product.In contrast, many triplet carbenes add with differing regioselectivity, giving the thermodynamically preferre
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Doi:10.1021/jm00321a010
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