Journal of Organic Chemistry p. 1690 - 1694 (1983)
Update date:2022-07-30
Topics:
Clerici, Angelo
Porta, Ombretta
Electron-withdrawing substituted carbonyl compounds which are allowed to react with 2 equiv of aqueous titanium trichloride selectively add to the carbonyl carbon atom of α,β-unsaturated aldehydes.Highly functionalized allylic pinacols are obtained in good yields under very simple experimental conditions.The fundamental role played by the titanium(III) ion is discussed.
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Doi:10.1039/a701749i
(1997)Doi:10.1021/acs.jmedchem.7b00179
(2017)Doi:10.1021/acs.jmedchem.8b00218
(2018)Doi:10.1039/c7cc08670a
(2017)Doi:10.1016/S0040-4039(99)01311-8
(1999)Doi:10.1248/cpb.49.629
(2001)
