Journal of the American Chemical Society p. 2628 - 2636 (1986)
Update date:2022-08-04
Topics:
Maslak, Przemyslaw
Guthrie, Robert D.
The radical anions of 4-nitrobenzyl phenyl ethers undergo cleavage at least 10E4 times faster than the radical anions of corresponding 4-nitrophenyl benzyl ethers despite a perceived thermodynamic advantage for the latter set of reactions.It is suggested that this results reflects a kinetic advantage for cleavage reactions which take place with regioconservation of spin density.
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