A radical-organometallic glycine synthon. Preparation of homochiral heterocyclic α-amino acids

DOI: 10.1016/S0040-4039(00)61614-3

Source and publish data:

Tetrahedron Letters p. 7119 - 7122 (1993)

Update date:2022-08-03

Topics:

Authors:

Lloris Lloris

Moreno-Manas

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Article abstract of DOI:10.1016/S0040-4039(00)61614-3

Co(Acac)₂ reacts with (1) and (d)-menthyl N-BOC-2-bromoglycinates to give (1)- and (d)-menthyl N-BOC-3-acetylnorvalinates, which are converted into homochiral 2-(3,5-dimethyl-4-pyrazolyl)glycine and 2-(3,5-dimethyl)-4-isoxazolylglycine.

Full text of DOI:10.1016/S0040-4039(00)61614-3

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