Journal of Organometallic Chemistry p. 13 - 18 (1986)
Update date:2022-08-03
Topics:
Coutrot, P.
Youssefi-Tabrizi, M.
Grison, C.
Diethyl-1-magnesium chloride methanephosphonate was obtained by an exchange reaction between diethyliodo methanephosphonate and isopropylmagnesium chloride in THF at -70 deg.C.Reactions of this novel Grignard reagent with various electrophiles are described, and compared with those of the analogous lithium or copper derivatives.Diethyl-1-magnesium chloride methanephosphonate is especially reactive towards phenylselenium halides and halogens.
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