Organic letters p. 2403 - 2406 (2001)
Update date:2022-09-26
Topics:
Semmelhack
Jiang
Ho
[reaction: see text] The amino sugar side chain (2) from C-1027Chr was synthesized in 12 steps from mannose. The key reactions are an internal displacement by nitrogen to introduce the cis amino group at C-4 and the methylation of an enolate at C-5.
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Doi:10.1002/jps.2600610113
(1972)Doi:10.1039/P19720000935
(1972)Doi:10.1016/j.dyepig.2019.107965
(2020)Doi:10.1055/s-1998-1885
(1998)Doi:10.1016/S0014-827X(01)01081-3
(2001)Doi:10.1007/BF01158506
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