Journal of Organometallic Chemistry p. C1 - C3 (1988)
Update date:2022-08-02
Topics:
Tarhouni, R.
Kirschleger, B.
Villieras, J.
The β-alkoxy monohalogenated carbenoids, C6H5CH(OSiMe3)CHXLi, can be obtained by bromine-lithium exchange from the corresponding bromohaloether in the presence of s-butllithium in a mixture of THF/ether/pentane at -130 deg C.The stability of the carbenoid (α-elimination and β-elimination) is described and discussed.
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