Journal of Organic Chemistry p. 14602 - 14610 (2019)
Update date:2022-07-30
Topics:
Crumbie, Robyn L.
Chalmers, Gareth
Bhadbhade, Mohan
Griffith, Renate
Nucleophilic addition of thiolates to diethyl acetylenedicarboxylate in chloroform at room temperature affords solely the meso dithioaddition product, whereas the addition of amines in ethanol gives only the corresponding (Z)-enamine, as confirmed by X-ra
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