Syntheses of heteroycles via palladium-catalyzed C-H activation/cyclization of diazonium salts (Part III): Phenanthridin-6-(5H)-ones

Article abstract of DOI:10.3987/COM-14-13051

A series of phenanthridin-6-(5H)-ones were synthesized through a palladium-catalyzed C-H activation/cyclization strategy using diazonium salts in good yields. The best conditions included Pd(OAc)2 as the catalyst, PPh3 as the ligand, toluene as the solvent, K2CO3 as the base and 60 oC as the optimal temperature.

Full text of DOI:10.3987/COM-14-13051

Current Data Parameters
NAME
EXPNO
PROCNO
HP-1
10
1
O
F2 - Acquisition Parameters
Date_
Time
INSTRUM
PROBHD
PULPROG
TD
20130828
17.53
spect
N
5 mm PABBO BB-
zg30
65536
SOLVENT
NS
CDCl3
8
2
DS
SWH
10330.578 Hz
0.157632 Hz
3.1719923 sec
40.3
FIDRES
AQ
RG
DW
48.400 usec
6.50 usec
300.5 K
1.00000000 sec
1
DE
TE
D1
TD0
======== CHANNEL f1 ========
NUC1
P1
1H
10.00 usec
PL1
0 dB
PL1W
SFO1
-1.#IND0000 W
500.1330885 MHz
F2 - Processing parameters
SI
32768
500.1300000 MHz
no
SF
WDW
SSB
LB
GB
PC
0
0 Hz
0
1.00
8.5
8.0
7.5
7.0
6.5
6.0
5.5
5.0
4.5
4.0
3.5
3.0
2.5
2.0
1.5
1.0
0.5
0.0
ppm

C13CPD CDCl3 {D:\2013} ZHL 37
Current Data Parameters
NAME
EXPNO
PROCNO
HP-1
11
1
F2 - Acquisition Parameters
Date_
Time
INSTRUM
PROBHD
PULPROG
TD
20130828
18.07
spect
5 mm PABBO BB-
zgpg30
65536
O
N
SOLVENT
NS
CDCl3
420
DS
SWH
4
29761.904 Hz
0.454131 Hz
1.1010548 sec
203
FIDRES
AQ
RG
DW
16.800 usec
6.50 usec
301.2 K
DE
TE
D1
0.60000002 sec
0.03000000 sec
1
D11
TD0
======== CHANNEL f1 ========
NUC1
P1
13C
9.30 usec
-1.00 dB
PL1
PL1W
SFO1
-1.#IND0000 W
125.7703643 MHz
======== CHANNEL f2 ========
CPDPRG2
NUC2
waltz16
1H
PCPD2
PL2
80.00 usec
0.80 dB
16.58 dB
17.00 dB
PL12
PL13
PL2W
-1.#IND0000 W
-1.#IND0000 W
-1.#IND0000 W
500.1320005 MHz
PL12W
PL13W
SFO2
F2 - Processing parameters
SI
32768
125.7577890 MHz
EM
SF
WDW
SSB
LB
0
0
1.00 Hz
1.40
GB
ppmPC
200
180
160
140
120
100
80
60
40
20
0

Current Data Parameters
NAME
EXPNO
PROCNO
DZT-20140313-HP-01161
11
1
F2 - Acquisition Parameters
Date_
Time
INSTRUM
PROBHD
PULPROG
TD
20140313
17.42
O
spect
5 mm PABBO BB-
zgpg30
65536
N
SOLVENT
NS
CDCl3
160
DS
SWH
2
29761.904 Hz
0.454131 Hz
1.1010548 sec
203
FIDRES
AQ
RG
DW
16.800 usec
6.50 usec
298.3 K
DE
TE
D1
0.60000002 sec
0.03000000 sec
1
Br
D11
TD0
======== CHANNEL f1 ========
NUC1
P1
13C
9.50 usec
-1.00 dB
PL1
PL1W
SFO1
-1.#IND0000 W
125.7703643 MHz
======== CHANNEL f2 ========
CPDPRG2
NUC2
waltz16
1H
PCPD2
PL2
80.00 usec
0 dB
PL12
16.05 dB
17.00 dB
-1.#IND0000 W
-1.#IND0000 W
-1.#IND0000 W
500.1320005 MHz
PL13
PL2W
PL12W
PL13W
SFO2
F2 - Processing parameters
SI
32768
125.7577890 MHz
EM
SF
WDW
SSB
LB
GB
PC
0
0
1.00 Hz
1.40
170 160 150 140 130 120 110 100
90
80
70
60
50
40
ppm

Current Data Parameters
NAME
EXPNO
PROCNO
DZT-20140313-HP-01161
10
1
F2 - Acquisition Parameters
Date_
Time
INSTRUM
PROBHD
PULPROG
TD
20140313
17.41
spect
5 mm PABBO BB-
zg30
65536
SOLVENT
NS
CDCl3
O
12
2
DS
SWH
10330.578 Hz
0.157632 Hz
3.1719923 sec
114
FIDRES
AQ
N
RG
DW
48.400 usec
6.50 usec
297.8 K
1.00000000 sec
1
DE
TE
D1
TD0
======== CHANNEL f1 ========
NUC1
P1
1H
9.00 usec
PL1
0 dB
Br
PL1W
SFO1
-1.#IND0000 W
500.1330885 MHz
F2 - Processing parameters
SI
32768
500.1300000 MHz
EM
SF
WDW
SSB
LB
GB
PC
0
0
0.30 Hz
1.00
9.0
8.5
8.0
7.5
7.0
6.5
6.0
5.5
ppm

Current Data Parameters
NAME
EXPNO
PROCNO
DZT-20140313-HP-01201
11
1
F2 - Acquisition Parameters
Date_
Time
INSTRUM
PROBHD
PULPROG
TD
20140314
8.11
O
spect
5 mm PABBO BB-
zgpg30
65536
N
SOLVENT
NS
CDCl3
131
DS
SWH
2
29761.904 Hz
0.454131 Hz
1.1010548 sec
203
FIDRES
AQ
RG
DW
16.800 usec
6.50 usec
295.7 K
DE
TE
D1
0.60000002 sec
0.03000000 sec
1
D11
TD0
======== CHANNEL f1 ========
NUC1
P1
13C
9.50 usec
-1.00 dB
PL1
PL1W
SFO1
-1.#IND0000 W
125.7703643 MHz
======== CHANNEL f2 ========
CPDPRG2
NUC2
waltz16
1H
PCPD2
PL2
80.00 usec
0 dB
PL12
16.05 dB
17.00 dB
-1.#IND0000 W
-1.#IND0000 W
-1.#IND0000 W
500.1320005 MHz
PL13
PL2W
PL12W
PL13W
SFO2
F2 - Processing parameters
SI
32768
125.7577890 MHz
EM
SF
WDW
SSB
LB
GB
PC
0
0
1.00 Hz
1.40
200
180
160
140
120
100
80
60
40
20
0
ppm

Current Data Parameters
NAME
EXPNO
PROCNO
DZT-20140313-HP-01201
10
1
F2 - Acquisition Parameters
Date_
Time
INSTRUM
PROBHD
PULPROG
TD
20140314
8.11
spect
5 mm PABBO BB-
zg30
O
65536
SOLVENT
NS
CDCl3
16
2
N
DS
SWH
10330.578 Hz
0.157632 Hz
3.1719923 sec
90.5
FIDRES
AQ
RG
DW
48.400 usec
6.50 usec
295.5 K
1.00000000 sec
1
DE
TE
D1
TD0
======== CHANNEL f1 ========
NUC1
P1
1H
9.00 usec
PL1
0 dB
PL1W
SFO1
-1.#IND0000 W
500.1330885 MHz
F2 - Processing parameters
SI
32768
500.1300000 MHz
EM
SF
WDW
SSB
LB
GB
PC
0
0
0.30 Hz
1.00
11
10
9
8
7
6
5
4
3
ppm

Current Data Parameters
NAME
EXPNO
PROCNO
DZT-20140313-HP-02211
11
1
F2 - Acquisition Parameters
Date_
Time
INSTRUM
PROBHD
PULPROG
TD
20140314
9.02
O
spect
5 mm PABBO BB-
zgpg30
65536
SOLVENT
NS
CDCl3
N
160
DS
SWH
2
29761.904 Hz
0.454131 Hz
1.1010548 sec
203
FIDRES
AQ
RG
DW
16.800 usec
6.50 usec
295.9 K
DE
TE
D1
2.00000000 sec
0.03000000 sec
1
D11
Cl
TD0
======== CHANNEL f1 ========
NUC1
P1
13C
9.50 usec
-1.00 dB
PL1
PL1W
SFO1
-1.#IND0000 W
125.7703643 MHz
======== CHANNEL f2 ========
CPDPRG2
NUC2
waltz16
1H
PCPD2
PL2
80.00 usec
0 dB
PL12
16.05 dB
17.00 dB
-1.#IND0000 W
-1.#IND0000 W
-1.#IND0000 W
500.1320005 MHz
PL13
PL2W
PL12W
PL13W
SFO2
F2 - Processing parameters
SI
32768
125.7577890 MHz
EM
SF
WDW
SSB
LB
GB
PC
0
0
1.00 Hz
1.40
170
160
150
140
130
120
110
100
90
80
70
60
50
ppm

Current Data Parameters
NAME
EXPNO
PROCNO
DZT-20140313-HP-02211
10
1
F2 - Acquisition Parameters
Date_
Time
INSTRUM
PROBHD
PULPROG
TD
20140314
8.55
spect
5 mm PABBO BB-
zg30
O
65536
SOLVENT
NS
CDCl3
16
2
N
DS
SWH
10330.578 Hz
0.157632 Hz
3.1719923 sec
101
FIDRES
AQ
RG
DW
48.400 usec
6.50 usec
294.9 K
1.00000000 sec
1
DE
TE
D1
TD0
Cl
======== CHANNEL f1 ========
NUC1
P1
1H
9.00 usec
PL1
0 dB
PL1W
SFO1
-1.#IND0000 W
500.1330885 MHz
F2 - Processing parameters
SI
32768
500.1300000 MHz
EM
SF
WDW
SSB
LB
GB
PC
0
0
0.30 Hz
1.00
9.0
8.5
8.0
7.5
7.0
6.5
6.0
5.5
ppm

Current Data Parameters
NAME
EXPNO
PROCNO
DZT-20140313-HP-02212
11
1
F2 - Acquisition Parameters
Date_
Time
INSTRUM
PROBHD
PULPROG
TD
20140314
9.09
O
spect
5 mm PABBO BB-
zgpg30
N
65536
SOLVENT
NS
CDCl3
103
DS
SWH
4
29761.904 Hz
0.454131 Hz
1.1010548 sec
203
FIDRES
AQ
RG
DW
16.800 usec
6.50 usec
296.3 K
DE
TE
OMe
D1
2.00000000 sec
0.03000000 sec
1
D11
TD0
======== CHANNEL f1 ========
NUC1
P1
13C
9.50 usec
-1.00 dB
PL1
PL1W
SFO1
-1.#IND0000 W
125.7703643 MHz
======== CHANNEL f2 ========
CPDPRG2
NUC2
waltz16
1H
PCPD2
PL2
80.00 usec
0 dB
PL12
16.05 dB
17.00 dB
-1.#IND0000 W
-1.#IND0000 W
-1.#IND0000 W
500.1320005 MHz
PL13
PL2W
PL12W
PL13W
SFO2
F2 - Processing parameters
SI
32768
125.7577890 MHz
EM
SF
WDW
SSB
LB
GB
PC
0
0
1.00 Hz
1.40
170
160
150
140
130
120
110
100
90
80
70
60
50
ppm

Current Data Parameters
NAME
EXPNO
PROCNO
DZT-20140313-HP-02212
10
1
F2 - Acquisition Parameters
Date_
Time
INSTRUM
PROBHD
PULPROG
TD
20140314
9.14
spect
O
5 mm PABBO BB-
zg30
65536
SOLVENT
NS
CDCl3
N
12
2
DS
SWH
10330.578 Hz
0.157632 Hz
3.1719923 sec
101
FIDRES
AQ
RG
DW
48.400 usec
6.50 usec
297.1 K
1.00000000 sec
1
DE
TE
D1
OMe
TD0
======== CHANNEL f1 ========
NUC1
P1
1H
9.00 usec
PL1
0 dB
PL1W
SFO1
-1.#IND0000 W
500.1330885 MHz
F2 - Processing parameters
SI
32768
500.1300000 MHz
EM
SF
WDW
SSB
LB
GB
PC
0
0
0.30 Hz
1.00
10.0 9.5
9.0
8.5
8.0
7.5
7.0
6.5
6.0
5.5
5.0
4.5
4.0
3.5
ppm

Current Data Parameters
NAME
EXPNO
PROCNO
DZT-20140409-hp-03271
11
1
C13CPD CDCl3 {D:\2014-1} ZHL 53
F2 - Acquisition Parameters
Date_
Time
INSTRUM
PROBHD
PULPROG
TD
20140409
14.59
spect
5 mm PABBO BB-
zgpg30
65536
O
N
SOLVENT
NS
CDCl3
256
DS
SWH
4
29761.904 Hz
0.454131 Hz
1.1010548 sec
203
FIDRES
AQ
RG
DW
16.800 usec
6.50 usec
301.5 K
DE
TE
D1
0.60000002 sec
0.03000000 sec
1
D11
TD0
======== CHANNEL f1 ========
NUC1
P1
13C
9.50 usec
-1.00 dB
O
PL1
PL1W
SFO1
-1.#IND0000 W
125.7703643 MHz
======== CHANNEL f2 ========
CPDPRG2
NUC2
waltz16
1H
PCPD2
PL2
80.00 usec
0 dB
PL12
16.05 dB
17.00 dB
-1.#IND0000 W
-1.#IND0000 W
-1.#IND0000 W
500.1320005 MHz
PL13
PL2W
PL12W
PL13W
SFO2
F2 - Processing parameters
SI
32768
125.7577890 MHz
EM
SF
WDW
SSB
LB
GB
PC
0
0
1.00 Hz
1.40
200
180
160
140
120
100
80
60
40
20
0
ppm

PROTON CDCl3 {D:\2014-1} ZHL 53
Current Data Parameters
NAME
EXPNO
PROCNO
DZT-20140409-hp-03271
10
1
F2 - Acquisition Parameters
Date_
Time
INSTRUM
PROBHD
PULPROG
TD
20140409
14.51
spect
5 mm PABBO BB-
zg30
65536
SOLVENT
NS
CDCl3
O
16
2
DS
SWH
10330.578 Hz
0.157632 Hz
3.1719923 sec
128
FIDRES
AQ
N
RG
DW
48.400 usec
6.50 usec
300.3 K
1.00000000 sec
1
DE
TE
D1
TD0
======== CHANNEL f1 ========
NUC1
P1
1H
9.00 usec
O
PL1
0 dB
PL1W
SFO1
-1.#IND0000 W
500.1330885 MHz
F2 - Processing parameters
SI
32768
500.1300000 MHz
EM
SF
WDW
SSB
LB
GB
PC
0
0
0.30 Hz
1.00
9.5
9.0
8.5
8.0
7.5
7.0
6.5
6.0
5.5
5.0
4.5
4.0
3.5
3.0
ppm

C13CPD CDCl3 {D:\2013} ZHL 31
Current Data Parameters
NAME
EXPNO
PROCNO
D-20131129-hp-11282
11
1
F2 - Acquisition Parameters
Date_
Time
INSTRUM
PROBHD
PULPROG
TD
20131129
12.01
spect
5 mm PABBO BB-
zgpg30
65536
CDCl3
64
O
SOLVENT
NS
DS
SWH
4
N
29761.904 Hz
FIDRES
AQ
0.454131 Hz
1.1010548 sec
203
RG
DW
16.800 usec
6.50 usec
296.9 K
DE
TE
D1
0.60000002 sec
0.03000000 sec
1
D11
TD0
O
======== CHANNEL f1 ========
NUC1
P1
13C
9.50 usec
-1.00 dB
PL1
PL1W
SFO1
-1.#IND0000 W
125.7703643 MHz
======== CHANNEL f2 ========
CPDPRG2
NUC2
waltz16
1H
PCPD2
PL2
80.00 usec
0 dB
PL12
16.05 dB
17.00 dB
-1.#IND0000 W
-1.#IND0000 W
-1.#IND0000 W
500.1320005 MHz
PL13
PL2W
PL12W
PL13W
SFO2
F2 - Processing parameters
SI
32768
125.7577890 MHz
no
SF
WDW
SSB
LB
0
0 Hz
0
GB
ppmPC
1.40
200
180
160
140
120
100
80
60
40
20
0

PROTON CDCl3 {D:\2013} ZHL 31
Current Data Parameters
NAME
EXPNO
PROCNO
D-20131129-hp-11282
10
1
F2 - Acquisition Parameters
Date_
Time
20131129
12.00
INSTRUM
spect
PROBHD 5 mm PABBO BB-
PULPROG
TD
zg30
65536
O
SOLVENT
NS
CDCl3
8
2
DS
N
SWH
FIDRES
AQ
10330.578 Hz
0.157632 Hz
3.1719923 sec
114
48.400 usec
6.50 usec
296.7 K
1.00000000 sec
1
RG
DW
DE
TE
D1
TD0
O
======== CHANNEL f1 ========
NUC1
P1
1H
9.00 usec
PL1
0 dB
PL1W
SFO1
-1.#IND0000 W
500.1330885 MHz
F2 - Processing parameters
SI
32768
500.1300000 MHz
EM
SF
WDW
SSB
LB
GB
PC
0
0
0.30 Hz
1.00
9.5
9.0
8.5
8.0
7.5
7.0
6.5
6.0
5.5
5.0
4.5
4.0
3.5
3.0
ppm

Current Data Parameters
NAME
EXPNO
PROCNO
D-20131215-hp-12051
11
1
C13CPD CDCl3 {D:\2013} ZHL 55
F2 - Acquisition Parameters
Date_
Time
INSTRUM
PROBHD
PULPROG
TD
20131215
10.15
spect
5 mm PABBO BB-
zgpg30
65536
CDCl3
256
SOLVENT
NS
DS
SWH
4
O
29761.904 Hz
FIDRES
AQ
0.454131 Hz
1.1010548 sec
203
N
RG
DW
16.800 usec
6.50 usec
303.4 K
DE
TE
D1
0.60000002 sec
0.03000000 sec
1
D11
TD0
======== CHANNEL f1 ========
OMe
NUC1
P1
13C
9.50 usec
-1.00 dB
PL1
PL1W
SFO1
-1.#IND0000 W
125.7703643 MHz
======== CHANNEL f2 ========
CPDPRG2
NUC2
waltz16
1H
PCPD2
PL2
80.00 usec
0 dB
PL12
16.05 dB
17.00 dB
-1.#IND0000 W
-1.#IND0000 W
-1.#IND0000 W
500.1320005 MHz
PL13
PL2W
PL12W
PL13W
SFO2
F2 - Processing parameters
SI
32768
125.7577890 MHz
EM
SF
WDW
SSB
LB
0
0
1.00 Hz
1.40
GB
ppmPC
200
180
160
140
120
100
80
60
40
20
0

PROTON CDCl3 {D:\2013} ZHL 55
Current Data Parameters
NAME
D-20131215-hp-12051
EXPNO
PROCNO
10
1
F2 - Acquisition Parameters
Date_
Time
20131215
10.06
INSTRUM
spect
PROBHD 5 mm PABBO BB-
PULPROG
TD
zg30
65536
SOLVENT
NS
CDCl3
8
2
DS
SWH
FIDRES
AQ
10330.578 Hz
0.157632 Hz
3.1719923 sec
114
48.400 usec
6.50 usec
302.4 K
1.00000000 sec
1
O
RG
N
DW
DE
TE
D1
TD0
======== CHANNEL f1 ========
NUC1
P1
1H
OMe
9.00 usec
PL1
0 dB
PL1W
SFO1
-1.#IND0000 W
500.1330885 MHz
F2 - Processing parameters
SI
32768
500.1300000 MHz
no
SF
WDW
SSB
LB
GB
PC
0
0 Hz
0
1.00
10.5 10.0 9.5
9.0
8.5
8.0
7.5
7.0
6.5
6.0
5.5
5.0
4.5
4.0
ppm

Current Data Parameters
NAME
EXPNO
PROCNO
D-20131215-hp-12061
C13CPD CDCl3 {D:\2013} ZHL 57
11
1
F2 - Acquisition Parameters
Date_
Time
INSTRUM
PROBHD
PULPROG
TD
20131215
10.32
spect
5 mm PABBO BB-
zgpg30
65536
CDCl3
96
O
SOLVENT
NS
N
DS
SWH
4
29761.904 Hz
FIDRES
AQ
0.454131 Hz
1.1010548 sec
203
RG
DW
16.800 usec
6.50 usec
303.3 K
DE
TE
D1
0.60000002 sec
0.03000000 sec
1
Br
D11
TD0
======== CHANNEL f1 ========
NUC1
P1
13C
9.50 usec
-1.00 dB
PL1
PL1W
SFO1
-1.#IND0000 W
125.7703643 MHz
======== CHANNEL f2 ========
CPDPRG2
NUC2
waltz16
1H
PCPD2
PL2
80.00 usec
0 dB
PL12
16.05 dB
17.00 dB
-1.#IND0000 W
-1.#IND0000 W
-1.#IND0000 W
500.1320005 MHz
PL13
PL2W
PL12W
PL13W
SFO2
F2 - Processing parameters
SI
32768
125.7577890 MHz
EM
SF
WDW
SSB
LB
0
0
1.00 Hz
1.40
GB
ppmPC
200
180
160
140
120
100
80
60
40
20
0

PROTON CDCl3 {D:\2013} ZHL 57
Current Data Parameters
NAME
EXPNO
PROCNO
D-20131215-hp-12061
10
1
F2 - Acquisition Parameters
Date_
Time
20131215
10.31
INSTRUM
spect
PROBHD 5 mm PABBO BB-
PULPROG
TD
zg30
65536
SOLVENT
NS
CDCl3
O
8
2
DS
SWH
FIDRES
AQ
10330.578 Hz
0.157632 Hz
3.1719923 sec
128
48.400 usec
6.50 usec
302.9 K
1.00000000 sec
1
N
RG
DW
DE
TE
D1
TD0
======== CHANNEL f1 ========
Br
NUC1
P1
1H
9.00 usec
PL1
0 dB
PL1W
SFO1
-1.#IND0000 W
500.1330885 MHz
F2 - Processing parameters
SI
32768
500.1300000 MHz
EM
SF
WDW
SSB
LB
GB
PC
0
0
0.30 Hz
1.00
9.0
8.5
8.0
7.5
7.0
6.5
6.0
5.5
5.0
4.5
4.0
ppm

C13CPD CDCl3 {D:\2013} ZHL 59
Current Data Parameters
NAME
EXPNO
PROCNO
D-20131215-hp-12092
11
1
F2 - Acquisition Parameters
Date_
Time
INSTRUM
PROBHD
PULPROG
TD
20131215
11.40
spect
5 mm PABBO BB-
O
zgpg30
65536
CDCl3
256
SOLVENT
NS
N
DS
SWH
4
29761.904 Hz
FIDRES
AQ
0.454131 Hz
1.1010548 sec
203
RG
DW
16.800 usec
6.50 usec
303.6 K
DE
TE
D1
0.60000002 sec
0.03000000 sec
1
D11
TD0
======== CHANNEL f1 ========
NUC1
P1
13C
9.50 usec
-1.00 dB
PL1
PL1W
SFO1
-1.#IND0000 W
125.7703643 MHz
======== CHANNEL f2 ========
CPDPRG2
NUC2
waltz16
1H
PCPD2
PL2
80.00 usec
0 dB
PL12
16.05 dB
17.00 dB
-1.#IND0000 W
-1.#IND0000 W
-1.#IND0000 W
500.1320005 MHz
PL13
PL2W
PL12W
PL13W
SFO2
F2 - Processing parameters
SI
32768
125.7577890 MHz
EM
SF
WDW
SSB
LB
0
0
1.00 Hz
1.40
GB
ppmPC
200
180
160
140
120
100
80
60
40
20
0

PROTON CDCl3 {D:\2013} ZHL 59
Current Data Parameters
NAME
EXPNO
PROCNO
D-20131215-hp-12092
10
1
F2 - Acquisition Parameters
Date_
Time
20131215
11.31
INSTRUM
spect
PROBHD 5 mm PABBO BB-
PULPROG
TD
zg30
65536
O
SOLVENT
NS
CDCl3
8
2
DS
N
SWH
FIDRES
AQ
10330.578 Hz
0.157632 Hz
3.1719923 sec
101
48.400 usec
6.50 usec
302.6 K
1.00000000 sec
1
RG
DW
DE
TE
D1
TD0
======== CHANNEL f1 ========
NUC1
P1
1H
9.00 usec
PL1
0 dB
PL1W
SFO1
-1.#IND0000 W
500.1330885 MHz
F2 - Processing parameters
SI
32768
500.1300000 MHz
no
SF
WDW
SSB
LB
GB
PC
0
0 Hz
0
1.00
11
10
9
8
7
6
5
4
3
ppm

Current Data Parameters
NAME
EXPNO
PROCNO
D-20131215-hp-12093
C13CPD CDCl3 {D:\2013} ZHL 60
11
1
F2 - Acquisition Parameters
Date_
Time
INSTRUM
PROBHD
PULPROG
TD
20131216
20.12
spect
5 mm PABBO BB-
zgpg30
65536
CDCl3
256
SOLVENT
NS
O
DS
SWH
4
29761.904 Hz
FIDRES
AQ
0.454131 Hz
1.1010548 sec
203
N
RG
DW
16.800 usec
6.50 usec
301.6 K
DE
TE
D1
0.60000002 sec
0.03000000 sec
1
D11
TD0
======== CHANNEL f1 ========
NUC1
P1
13C
Cl
9.50 usec
-1.00 dB
PL1
PL1W
SFO1
-1.#IND0000 W
125.7703643 MHz
======== CHANNEL f2 ========
CPDPRG2
NUC2
waltz16
1H
PCPD2
PL2
80.00 usec
0 dB
PL12
16.05 dB
17.00 dB
-1.#IND0000 W
-1.#IND0000 W
-1.#IND0000 W
500.1320005 MHz
PL13
PL2W
PL12W
PL13W
SFO2
F2 - Processing parameters
SI
32768
125.7577890 MHz
EM
SF
WDW
SSB
LB
0
0
1.00 Hz
1.40
GB
ppmPC
170 160 150 140 130 120 110 100 90 80 70 60 50 40 30 20 10

PROTON CDCl3 {D:\2013} ZHL 60
Current Data Parameters
NAME
EXPNO
PROCNO
D-20131215-hp-12093
10
1
F2 - Acquisition Parameters
Date_
Time
20131216
20.03
INSTRUM
spect
PROBHD 5 mm PABBO BB-
PULPROG
TD
zg30
65536
O
SOLVENT
NS
CDCl3
8
2
DS
N
SWH
FIDRES
AQ
10330.578 Hz
0.157632 Hz
3.1719923 sec
128
48.400 usec
6.50 usec
300.5 K
1.00000000 sec
1
RG
DW
DE
TE
D1
TD0
Cl
======== CHANNEL f1 ========
NUC1
P1
1H
9.00 usec
PL1
0 dB
PL1W
SFO1
-1.#IND0000 W
500.1330885 MHz
F2 - Processing parameters
SI
32768
500.1300000 MHz
no
SF
WDW
SSB
LB
GB
PC
0
0 Hz
0
1.00
10.5 10.0 9.5
9.0
8.5
8.0
7.5
7.0
6.5
6.0
5.5
5.0
4.5
4.0
ppm

Current Data Parameters
NAME
EXPNO
PROCNO
D-20131215-hp-12101
C13CPD CDCl3 {D:\2013} ZHL 1
11
1
F2 - Acquisition Parameters
Date_
Time
INSTRUM
PROBHD
PULPROG
TD
20131216
O
20.24
spect
5 mm PABBO BB-
zgpg30
65536
CDCl3
256
N
SOLVENT
NS
Br
DS
SWH
4
29761.904 Hz
FIDRES
AQ
0.454131 Hz
1.1010548 sec
203
RG
DW
16.800 usec
6.50 usec
301.6 K
DE
TE
D1
0.60000002 sec
0.03000000 sec
1
D11
TD0
======== CHANNEL f1 ========
NUC1
P1
13C
9.50 usec
-1.00 dB
PL1
PL1W
SFO1
-1.#IND0000 W
125.7703643 MHz
======== CHANNEL f2 ========
CPDPRG2
NUC2
waltz16
1H
PCPD2
PL2
80.00 usec
0 dB
PL12
16.05 dB
17.00 dB
-1.#IND0000 W
-1.#IND0000 W
-1.#IND0000 W
500.1320005 MHz
PL13
PL2W
PL12W
PL13W
SFO2
F2 - Processing parameters
SI
32768
125.7577890 MHz
EM
SF
WDW
SSB
LB
0
0
1.00 Hz
1.40
GB
ppmPC
170 160 150 140 130 120 110 100 90 80 70 60 50 40 30 20 10

PROTON CDCl3 {D:\2013} ZHL 1
Current Data Parameters
NAME
EXPNO
PROCNO
D-20131215-hp-12101
10
1
F2 - Acquisition Parameters
Date_
Time
20131216
20.16
INSTRUM
spect
O
PROBHD 5 mm PABBO BB-
PULPROG
TD
zg30
65536
N
SOLVENT
NS
CDCl3
8
2
DS
Br
SWH
FIDRES
AQ
10330.578 Hz
0.157632 Hz
3.1719923 sec
114
RG
DW
48.400 usec
6.50 usec
300.6 K
1.00000000 sec
1
DE
TE
D1
TD0
======== CHANNEL f1 ========
NUC1
P1
1H
9.00 usec
PL1
0 dB
PL1W
SFO1
-1.#IND0000 W
500.1330885 MHz
F2 - Processing parameters
SI
32768
500.1300000 MHz
no
SF
WDW
SSB
LB
GB
PC
0
0 Hz
0
1.00
10.5 10.0 9.5
9.0
8.5
8.0
7.5
7.0
6.5
6.0
5.5
5.0
4.5
4.0
ppm

Current Data Parameters
NAME
EXPNO
PROCNO
DZT-20140313-HP-12301
11
1
F2 - Acquisition Parameters
Date_
Time
INSTRUM
PROBHD
PULPROG
TD
20140313
17.36
O
spect
5 mm PABBO BB-
zgpg30
N
65536
SOLVENT
NS
CDCl3
256
DS
SWH
2
29761.904 Hz
0.454131 Hz
1.1010548 sec
203
FIDRES
AQ
RG
DW
16.800 usec
6.50 usec
298.5 K
DE
TE
D1
0.60000002 sec
0.03000000 sec
1
D11
TD0
======== CHANNEL f1 ========
NUC1
P1
13C
9.50 usec
-1.00 dB
PL1
PL1W
SFO1
-1.#IND0000 W
125.7703643 MHz
======== CHANNEL f2 ========
CPDPRG2
NUC2
waltz16
1H
PCPD2
PL2
80.00 usec
0 dB
PL12
16.05 dB
17.00 dB
-1.#IND0000 W
-1.#IND0000 W
-1.#IND0000 W
500.1320005 MHz
PL13
PL2W
PL12W
PL13W
SFO2
F2 - Processing parameters
SI
32768
125.7577890 MHz
EM
SF
WDW
SSB
LB
GB
PC
0
0
1.00 Hz
1.40
170 160 150 140 130 120 110 100
90
80
70
60
50
40
ppm

Current Data Parameters
NAME
EXPNO
PROCNO
DZT-20140313-HP-12301
10
1
F2 - Acquisition Parameters
Date_
Time
INSTRUM
PROBHD
PULPROG
TD
20140313
17.28
spect
5 mm PABBO BB-
zg30
65536
SOLVENT
NS
CDCl3
16
2
DS
SWH
O
10330.578 Hz
0.157632 Hz
3.1719923 sec
101
FIDRES
AQ
RG
N
DW
48.400 usec
6.50 usec
297.4 K
1.00000000 sec
1
DE
TE
D1
TD0
======== CHANNEL f1 ========
NUC1
P1
1H
9.00 usec
PL1
0 dB
PL1W
SFO1
-1.#IND0000 W
500.1330885 MHz
F2 - Processing parameters
SI
32768
500.1300000 MHz
EM
SF
WDW
SSB
LB
GB
PC
0
0
0.30 Hz
1.00
9.0
8.5
8.0
7.5
7.0
6.5
6.0
5.5
ppm

Current Data Parameters
NAME
EXPNO
PROCNO
DZT-20140516-hp-05131
11
1
C13CPD CDCl3 {D:\2014-1} ZHL 48
F2 - Acquisition Parameters
Date_
Time
INSTRUM
PROBHD
PULPROG
TD
20140516
16.09
spect
5 mm PABBO BB-
zgpg30
65536
SOLVENT
NS
CDCl3
129
DS
SWH
4
29761.904 Hz
0.454131 Hz
1.1010548 sec
203
FIDRES
AQ
O
RG
DW
16.800 usec
6.50 usec
300.9 K
N
DE
TE
F
D1
0.60000002 sec
0.03000000 sec
1
D11
TD0
======== CHANNEL f1 ========
NUC1
P1
13C
9.50 usec
-1.00 dB
PL1
PL1W
SFO1
-1.#IND0000 W
125.7703643 MHz
======== CHANNEL f2 ========
CPDPRG2
NUC2
waltz16
1H
PCPD2
PL2
80.00 usec
0 dB
PL12
16.05 dB
17.00 dB
-1.#IND0000 W
-1.#IND0000 W
-1.#IND0000 W
500.1320005 MHz
PL13
PL2W
PL12W
PL13W
SFO2
F2 - Processing parameters
SI
32768
125.7577890 MHz
EM
SF
WDW
SSB
LB
GB
PC
0
0
1.00 Hz
1.40
200
180
160
140
120
100
80
60
40
20
0
ppm

PROTON CDCl3 {D:\2014-1} ZHL 48
Current Data Parameters
NAME
EXPNO
PROCNO
DZT-20140516-hp-05131
10
1
F2 - Acquisition Parameters
Date_
Time
INSTRUM
PROBHD
PULPROG
TD
20140516
16.07
spect
5 mm PABBO BB-
zg30
65536
SOLVENT
NS
CDCl3
8
2
DS
SWH
10330.578 Hz
0.157632 Hz
3.1719923 sec
161
FIDRES
AQ
O
RG
DW
48.400 usec
6.50 usec
300.2 K
1.00000000 sec
1
N
DE
TE
F
D1
TD0
======== CHANNEL f1 ========
NUC1
P1
1H
9.00 usec
PL1
0 dB
PL1W
SFO1
-1.#IND0000 W
500.1330885 MHz
F2 - Processing parameters
SI
32768
500.1300000 MHz
EM
SF
WDW
SSB
LB
GB
PC
0
0
0.30 Hz
1.00
13
12
11
10
9
8
7
6
5
4
3
2
1
0
ppm

Current Data Parameters
NAME
EXPNO
PROCNO
DZT-20140516-hp-05132
11
1
C13CPD CDCl3 {D:\2014-1} ZHL 47
F2 - Acquisition Parameters
Date_
Time
INSTRUM
PROBHD
PULPROG
TD
20140516
16.00
spect
5 mm PABBO BB-
zgpg30
65536
O
SOLVENT
NS
CDCl3
80
4
DS
SWH
N
29761.904 Hz
0.454131 Hz
1.1010548 sec
203
FIDRES
AQ
COOMe
RG
DW
16.800 usec
6.50 usec
300.6 K
DE
TE
D1
0.60000002 sec
0.03000000 sec
1
D11
TD0
======== CHANNEL f1 ========
NUC1
P1
13C
9.50 usec
-1.00 dB
PL1
PL1W
SFO1
-1.#IND0000 W
125.7703643 MHz
======== CHANNEL f2 ========
CPDPRG2
NUC2
waltz16
1H
PCPD2
PL2
80.00 usec
0 dB
PL12
16.05 dB
17.00 dB
-1.#IND0000 W
-1.#IND0000 W
-1.#IND0000 W
500.1320005 MHz
PL13
PL2W
PL12W
PL13W
SFO2
F2 - Processing parameters
SI
32768
125.7577890 MHz
EM
SF
WDW
SSB
LB
GB
PC
0
0
1.00 Hz
1.40
180 170 160 150 140 130 120 110 100 90
80
70
60
50
40
30
ppm

PROTON CDCl3 {D:\2014-1} ZHL 47
Current Data Parameters
NAME
EXPNO
PROCNO
DZT-20140516-hp-05132
10
1
F2 - Acquisition Parameters
Date_
Time
INSTRUM
PROBHD
PULPROG
TD
20140516
15.59
spect
5 mm PABBO BB-
zg30
65536
SOLVENT
NS
CDCl3
8
2
O
DS
SWH
10330.578 Hz
0.157632 Hz
3.1719923 sec
144
FIDRES
AQ
N
RG
COOMe
DW
48.400 usec
6.50 usec
300.4 K
1.00000000 sec
1
DE
TE
D1
TD0
======== CHANNEL f1 ========
NUC1
P1
1H
9.00 usec
PL1
0 dB
PL1W
SFO1
-1.#IND0000 W
500.1330885 MHz
F2 - Processing parameters
SI
32768
500.1300000 MHz
EM
SF
WDW
SSB
LB
GB
PC
0
0
0.30 Hz
1.00
9.5
9.0
8.5
8.0
7.5
7.0
6.5
6.0
5.5
5.0
4.5
4.0
ppm