Bull. Russ. Acad. Sci. Div. Chem. Sci. (Engl. Transl.) p. 1957 - 1959 (1992)
Update date:2022-08-02
Topics:
Gavrilenko, V. V.
Chekulaeva, L. A.
Savitskaya, I. A.
Garbuzova, I. A.
A convenient and practical method is proposed for the synthesis of lanthanide and yttrium alkoxides.The method involves dissolving the metals or their hydrides in a solution of dry HCl in the corresponding alcohol, with subsequent dehalogenation of the LnCl3 solution by an equivalent amount of alkali metal (Na, Li).The rareearth alkoxides are easily converted into acetylacetonates Ln(acac)3 by the action of acetylacetone. Keywords: lanthanide alkoxides, lanthanide acetylacetonates, synthesis, yttrium, lanthanum, praseodymium, lutetium.
Contact:+86-15995924277
Address:WuZhongOu suzhou new south road 89
Contact:86-571-86737118-8689
Address:No.69, 12 Street, HEDA, Hangzhou, Zhejiang, China
Guangzhou Puho Pharmaceutical Technology Co. Ltd.
Contact:86-20-29848035/29848075
Address:No.166, Chaoyang East Road, Panyu District, Guangzhou City, Guangdong Province
Laizhou City Laiyu Chemical CO.,Ltd
Contact:+86-535-2719337/2719339
Address:Chenggang road zhuyou laizhou City Shangdong China
Tianjin Hedong Red Cliff Chemical Reagent Factory
Contact:+86-022-84780548
Address:Li Ming Zhuang Gong Ye Yuan,Dongli District,Tianjin,China
Doi:10.1016/S0039-128X(01)00110-6
(2001)Doi:10.1002/hlca.19880710225
(1988)Doi:10.1246/bcsj.74.1717
(2001)Doi:10.1021/jm010256v
(2001)Doi:10.1021/jo020319x
(2003)Doi:10.1039/b604632k
(2006)
