Tetrahedron Letters p. 6451 - 6454 (2001)
Update date:2022-08-03
Topics:
Xie, Xu
Freed, Dana A.
Kozlowski, Marisa C.
N-Monoalkyl 1,5-diaza-cis-decalins were synthesized in high yield and purity by derivatization of tetrahydronaphthyridine followed by reduction to the saturated system. The position of the conformational equilibrium between the chair-chair inversion forms of a series of four N-monoalkyl of 1,5-diaza-cis-decalins was measured and was directly related to the size of the N-alkyl group.
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