Tetrahedron Letters p. 4203 - 4206 (1985)
Update date:2022-08-03
Topics:
Harano, Kazunobu
Ohizumi, Norihide
Hisano, Takuzo
The fractional distillation of O-(2-alkenyl or 2-cycloalkenyl) S-alkyl dithiocarbonates (xanthates) affords 2-alkenyl or 2-cycloalkenyl alkyl sulfides.The reaction involves the <3,3>-sigmatropic rearrangement of the xanthates to produce S-(2-alkenyl or 2-cycloalkenyl) S-alkyl dithiocarbonates followed by extrusion of carbon oxysulfide to give 2-alkenyl or 2-cycloalkenyl alkyl sulfides.
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(2001)
