Monatshefte fur Chemie p. 1159 - 1170 (1994)
Update date:2022-08-05
Topics:
Wannagat, U.
Damrath, V.
Harder, U.
Substitution of the (CH3)2CH=CH group by (CH3)2C=N in linalool as well as by the (CH3)2CH-CH2 group in linalool and in sila-linalool does not lead to noticeable changes of their scent qualities.On the contrary, substitution of the OH group at the tertiary C atom by NH2 or CH3 - hydride isosteric to OH according to Grimm - affords fishy or etheric instead of the original flowery smells thus indicating a transition to different basic classes of odor.Similar results were obtained with the linalool-like scents of benzyldimethylcarbinol and phenylethyldimethylcarbinol.Therefor the theory of Amoore, after which only shape and size of molecules are ruling their odor qualities, must be called in question. - Keywords: Perfumes; Sila Perfumes; Isosteric Compounds; Silazanes; Olfactoric Theories.
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