Journal of Fluorine Chemistry p. 169 - 172 (1997)
Update date:2022-08-03
Topics:
Clark, James H.
Tavener, Stewart J.
The trifluoromethanethiolate anion may be generated in situ by the reaction of thiophosgene with potassium fluoride in acetonitrile. This system is used to prepare trifluoromethyl aryl sulfides from activated fluoro- and chloroaromatic substrates via nucleophilic substitution.
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