International Journal of Chemical Kinetics p. 413 - 419 (1996)
Update date:2022-09-26
Topics:
Bajpai
Shukla
Upadhyay
An inhibition effect of PdCl2 on the rate of oxidation of sugars, by alkaline hexacyano-ferrate(III) has been observed. The order of reactions in hexacyanoferrate(III) and OH- is zero and unity, respectively, while that in sugars decreases from unity at higher sugar concentration. The kinetic data and spectrophotometric evidence support the formation of {PdII - (sugar)} and {PdII - sugar)2} complexes and their resistance to react with Fe(CN)63-.
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