Flash Vacuum Pyrolysis of Alkoxycarbonyl/Sulfinyl Stabilised Phosphorus Ylides: Generation and Intramolecular Insertion of Alkoxycarbonyl(sulfenyl)carbenes

DOI: 10.1039/c39940000805

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 805 - 806 (1994)

Update date:2022-08-05

Topics:

Authors:

Aitken, R. Alan

Drysdale, Martin J.

Ryan, Bruce M.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39940000805

Flash vacuum pyrolysis of phosphorus ylides stabilised both by ester and sulfinyl groups results mainly in extrusion of Ph3PO to generate alkoxycarbonyl(sulfenyl)carbenes; these undergo intramolecular insertion into CH of the alkoxycarbonyl group giving β-lactones which under the conditions lose CO2 to afford alkenyl sulfides.

Full text of DOI:10.1039/c39940000805

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Benzene, 1-chloro-4-(1-propenylthio)-

Cas No:39815-01-5

R&D Labs maybe for 39815-01-5

SuZhou Ascepion Pharmaceuticals, Inc.(expird)

Contact:0512-86881668

Address:Building C,68Xingqing Road,Suzhou,China.
Pengchen New Material Technology Co., Ltd.

Contact:+86-512-63680537

Address:99.6 km of national road 318, Meiyan Community,Pingwang Town, Wujiang District, Suzhou 215225
Shanghai Hongbang Medical Technology CO.,. Ltd

Contact:13671516988 /18917636693

Address:Room1, No67 Building, Yongde Road369, Wujing Town, Minhang Districy, Shanghai CIty, China.
chemonlinephramacistdepot

Contact:86-607-68073220

Address:1 ave na road jiahua st
ZiBO KuoDing Trade company Ltd

website:http://www.sdzbkd.com

Contact:86-13361591822

Address:GongQingTuan road

Relevant to this article

Synthesis of a tetramethoxy and an amphiphilic tetrahydroxy hemilabile N,P,N-ligand. Coordination behavior towards rhodium(I) and application to hydroformylation of styrene or hydrogenation of trans-cinnamaldehyde

Doi:10.1016/S0022-328X(01)01116-0
(2001)
Stereocontrolled construction of rigid tricyclic bis(α-amino acid) derivatives by RU(II)-catalyzed cascade and Diels-Alder reactions

Doi:10.1039/b103254m
(2001)
Palladium(II) complexes with the bidentate iminophosphine ligand [Ph₂PCH₂C(Ph)=N(2,6-Me₂C₆H₃)]

Doi:10.1039/b102476k
(2001)
Os₅(CO)₁₈(CNBu^t)₂(Cl)₂: A complex with a linear chain of five osmium atoms

Doi:10.1021/om010948h
(2002)
Organosulfur compounds as potential fungicides: The preparation and properties of some substituted benzyl 2-hydroxyethyl oligosulfides

Doi:10.1080/10426500008043656
(2000)
Doi:10.1016/S0040-4039(01)94251-0
(1972)

Article Doi