Organic letters p. 355 - 357 (2002)
Update date:2022-08-04
Topics:
Dohi, Hirofumi
Nishida, Yoshihiro
Furuta, Yuki
Uzawa, Hirotaka
Yokoyama, Shin-ichiro
Ito, Saori
Mori, Hiroshi
Kobayashi, Kazukiyo
Galacto-type trehalose, a "C-4 epimer of trehalose", possesses a stereochemical structure around the alpha(1-1)-linkage analogous to that of the globobiosyl alpha(1-4)-linkage in Gb(2) and Gb(3) ceramides, which are known as the ligands of Shiga toxins produced by pathogenic E. coli. This paper presents evidence supporting the new idea of using a trehalosyl alpha(1-1)-linkage as a substitute for the galactobiosyl alpha(1-4)-linkage.
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