Journal of Fluorine Chemistry p. 191 - 194 (1998)
Update date:2022-08-04
Topics:
Brooke, Gerald M.
Cooper, Julian A.
Howard, Judith A. K.
Yufit, Dmitri S.
Pentafluorophenol reacts with sodium trichloroacetate in monoglyme in a Reimer-Tiemann reaction to give not only pentafluorophenyl orthoformate (6) but also a previously unknown 'abnormal' type of product, tetrakis(pentafluorophenoxy)ethene (5), one possible formation of which could be by dimerisation of an intermediate carbene.
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