Total Synthesis of Dihydrovitamin DHV3 and Dihydrotachysterol DHT3. Application of the Low-Valent Titanium-Induced Reductive Elimination

DOI: 10.1021/jo00392a012

Source and publish data:

Journal of Organic Chemistry p. 3560 - 3566 (1987)

Update date:2022-08-04

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Authors:

Solladie, Guy

Hutt, Jean

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Article abstract of DOI:10.1021/jo00392a012

Optically active ring A synthons 6, 11, 13, and 14, precursors of DHV3 and DHT3, were synthetized from (-)- and (+)-carvone.Application of the low-valent titanium-induced reductive elimination gave a new synthetic approach to vitamin D3 analogues, as show

Full text of DOI:10.1021/jo00392a012

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