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Catalysis Science & Technology
DOI: 10.1039/C5CY00267B
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catalyst. In addition, the study of chemoselective acylation of 1,3ꢀ
butandiol with dodecanoic acid with varied mesoporous solid
acids including both 1a and 1b implies that there is a compromise
between the reaction selectivity and the surface physicochemical
properties of the employed catalyst. Our results clearly show that
the catalyst having high surface hydrophilic nature gives high
selectivity toward the formation of monoꢀacylated products
whereas those with relatively high hydrophobic characteristics
showed enhanced selectivity toward formation of diꢀacylated
10 products. We speculate the results of this study would provide
more information in designing novel types of sophisticated hybrid
solid acid catalysts with tuneable selectivity in the described
reaction by just adjusting their surface physicochemical
Properties of the employed catalyst.
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15 Notes and references
a Prof. Dr. Babak Karimi, Hamid M. Mirzaei, and Akbar Mobaraki
Department of Chemistry, Institute for Advanced Studies in Basic
Sciences (IASBS),Zanjan 45137-6731 (Iran)
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Fax: (+98)-241-415-3232
20 E-mail:karimi@iasbs.ac.ir
b Prof. Hojatollah Vali
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Department of Anatomy and Cell Biology and Facility for Electron
Microscopy Research, McGill University, Montreal, Quebec, H3A 2A7
Canada.
25 † Electronic Supplementary Information (ESI) available: [procedures for
catalysts preparation, porosimetry data, TG analysis, TEM, 1HNMR,
13CNMR]. See DOI: 10.1039/b000000x/
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