One-step synthesis of alkenyl ketone complexes from CP*RhCl2(PPh3), alkyne and H2O in the presence of KPF6

DOI: 10.1039/b108953f

Source and publish data:

Chemical Communications p. 128 - 129 (2002)

Update date:2022-08-05

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Authors:

Ogata, Kenichi

Kuge, Katsuaki

Tatsumi, Kazuyuki

Yamamoto, Yasuhiro

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Article abstract of DOI:10.1039/b108953f

The reaction of Cp*RhCl₂(PPh₃) 1 with 1-alkyne and H₂O in the presence of KPF₆ afforded the alkenyl ketone complex [Cp*Rh(PPh₃)(CPh=CHCOCH₂R)](PF₆) [R = p-tolyl (3a), R = Ph (3b)

Full text of DOI:10.1039/b108953f

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Product name:[(C₅Me₅)Rh(triphenylphosphine)(C(C₆H₄-p-Me)CHC(O)CH₂C₆H₄-p-Me)](PF₆)

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