Photosensitized Electron Transfer from Azoalkanes: Generation, Fragmentation, and Rearrangement of Radical Cations Structurally Related to Dicyclopentadiene

DOI: 10.1021/jo00072a008

Source and publish data:

Journal of Organic Chemistry p. 5310 - 5315 (1993)

Update date:2022-08-04

Topics:

Authors:

Adam, Waldemar

Sendelbach, Juergen

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00072a008

The azoalkanes 1a-c extrude nitrogen upon photosensitized electron transfer (PET) to yield 1,3-radical cation intermediates 2(.+), which undergo interesting transformations.Electron back transfer (BET) affords the unrearranged housanes 2, but significant

Full text of DOI:10.1021/jo00072a008

Products guided by the article

Product name:1,2,5,5-Tetramethylcyclopenta-1,3-diene

Cas No:4249-12-1

R&D Labs maybe for 4249-12-1

Zhejiang Chemicals Import & Export Corporation

Contact:86-571-87043088

Address:No.37,Qingchun Road,Hangzhou,China
Shanxi Sanwei Group Co.,Ltd

Contact:0086-357-6662688

Address:Zhaocheng town, Hongtong County, Linfen City, Shanxi Province
Zhejiang Chemicals Import & Export Corporation

Contact:86-571-87043088

Address:No.37,Qingchun Road,Hangzhou,China
Zhuhai Jiacheng Biological Technology Co., Ltd

Contact:0756-8800233

Address:room 222, Lianhua road , Gongbei ,Zhuhai, Guangdong ,China
HANGZHOU ZHONGCHANG SCIENTIFIC CO.,LTD

Contact:+86-571-88932183

Address:Hangzhou

Relevant to this article

Synthesis of Tetrahydroquinolines via Borrowing Hydrogen Methodology Using a Manganese PN³Pincer Catalyst

Doi:10.1021/acs.orglett.0c02905
(2020)
Letter: Synthesis of 1-N-((s)-4-amino-2-hydroxybutyryl)-3',4'-dideoxyneamine.

Doi:10.7164/antibiotics.26.304
(1973)
Screening on the use of Kluyveromyces marxianus CBS 6556 growing cells as enantioselective biocatalysts for ketone reductions

Doi:10.1016/j.tetasy.2011.11.014
(2011)
Stereocontrol at the steady state in radical cyclizations of acyclic dihalides

Doi:10.1021/jo011056u
(2002)
Doi:10.1021/ja01651a036
(1954)
Catalytic, enantioselective aldol additions to ketones

Doi:10.1021/ja025670e
(2002)

Article Doi