Reduction of five-membered α,β-unsaturated lactones and related compounds with the Ni2+/BH4- system

DOI: 10.1248/cpb.39.1167

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 1167 - 1170 (1991)

Update date:2022-08-05

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Authors:

Abe Abe

Fujisaki

Sumoto Sumoto

Miyano Miyano

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Article abstract of DOI:10.1248/cpb.39.1167

The reductions of an α,β-unsaturated lactone (5) and lactam (7) with the Ni²⁺/BH₄^- system resulted in the formation of cis-hydrogenated products (8a and 9a) with high stereoselectivity. The cis products (8a and 9a) were ea

Full text of DOI:10.1248/cpb.39.1167

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