Journal of the American Chemical Society p. 14098 - 14103 (2019)
Update date:2022-07-29
Topics:
Trost, Barry M.
Spohr, Simon M.
Rolka, Alessa B.
Kalnmals, Christopher A.
The synthesis of P-chiral compounds is challenging, especially since useful catalytic methods for preparing such molecules are scarce. Herein we disclose a desymmetrization that employs phosphinic acids as prochiral nucleophiles in a Pd-catalyzed asymmetr
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