Stereoselective synthesis of syn-2,7-disubstituted-4,5-oxepenes

DOI: 10.1016/S0040-4020(02)00046-7

Source and publish data:

Tetrahedron p. 1913 - 1919 (2002)

Update date:2022-08-04

Topics:

Authors:

Díaz, David D

Betancort, Juan M

Crisóstomo, Fernando R.P

Martín, Tomás

Martín, Víctor S

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Article abstract of DOI:10.1016/S0040-4020(02)00046-7

An efficient synthesis of the title compounds as pure enantiomers is reported. The method is based on the intramolecular trapping of a carbocation generated by acid treatment of exo-Co₂(CO)₆-propargyl alcohols by a stereochemically c

Full text of DOI:10.1016/S0040-4020(02)00046-7

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