Hetero-Cope rearrangement for the synthesis of potassium 5-tert-butyl-2-(tert-butyl-aminoxy)-benzoate, a highly water-soluble stable free radical

DOI: 10.1016/S0040-4039(02)00311-8

Source and publish data:

Tetrahedron Letters p. 2613 - 2614 (2002)

Update date:2022-07-31

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Authors:

Marx, Lucien

Rassat, André

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Article abstract of DOI:10.1016/S0040-4039(02)00311-8

The hetero-Cope rearrangement of 4-tert-butyl-phenyl-tert-butylhydroxylamine provides an easy access to the corresponding ortho-bromoaniline, converted to the new highly water-soluble nitroxide, potassium 5-tert-butyl-2-(tert-butyl-aminoxy)-benzoate. The parent carboxylic acid was found to be very persistent in water at pH 1.

Full text of DOI:10.1016/S0040-4039(02)00311-8

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