Journal of Organometallic Chemistry p. 43 - 50 (1981)
Update date:2022-08-05
Topics:
Tomadze, A. V.
Yablokova, N. V.
Yablokov, V. A.
Razuvaev, G. A.
The kinetics and mechanism of thermal decomposition of R1R2(H)SiOOR3 silylperoxides have been studied.It has been shown that peroxides generated diorganosilanones, R1R2Si=O, with a high yield in the temperature range 130-180 deg C.A mechanism is suggested for the silanone formation.The interaction of silanones with cyclosiloxanes, triethylsilane, α-methylstyrene has been investigated as well as the cyclisation of silanones.
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