Organic letters p. 2637 - 2640 (2002)
Update date:2022-08-05
Topics:
Chow, Chun P
Shea, Kenneth J
Sparks, Steven M
[reaction: see text] The type 2 intramolecular N-acylnitroso Diels-Alder reaction has been employed for the synthesis of substituted bridged bicyclic oxazinolactams. Upon oxidation of hydroxamic acid 6, a 3-benzylated oxazinolactam (7) was synthesized with complete diastereoselectivity. Elaboration of cycloadduct 7 liberated a cis-3,7-disubstituted azocin-2-one (9).
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Doi:10.1002/1521-3773(20020617)41:12<2144::AID-ANIE2144>3.0.CO;2-E
(2002)Doi:10.1002/1521-3749(200206)628:6<1433::AID-ZAAC1433>3.0.CO;2-H
(2002)Doi:10.1016/S0277-5387(02)01026-4
(2002)Doi:10.1021/jo025897s
(2002)Doi:10.1016/S0040-4039(00)00571-2
(2000)Doi:10.1246/bcsj.61.2681
(1988)