Chemistry Letters p. 1081 - 1082 (1983)
Update date:2022-08-05
Topics:
Hosokawa, Takahiro
Inui, Shiro
Murahashi, Shun-Ichi
Treatment of α-isophorone (1) with t-BuOOH in the presence of palladium(II) or copper(I) catalyst gives ketoisophorone (2) selectively.A similar treatment of silyl enol ether 7 derived from 1 affords 6-hydroxylisophorone 8.
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