Journal of Organometallic Chemistry p. 65 - 76 (1980)
Update date:2022-08-04
Topics:
Blum, Y.
Becker, Y.
Shvo, Y.
N-Benzyloxypiperidine exhibits an unexpected type of reactivity toward Fe2(CO)9.Benzaldehyde and N-formylpiperidine are formed, most probably in a concerted manner, as revealed by deuterium-labeling experiments.Several mechanistic details of this reaction have been elucidated.The nature of the reaction contrasts with that of N-propyloxy-N-methylaniline, which upon treatment with Fe2(CO)9 undergoes insertion of a CO group into the N-O bond to generate a carbamate.
View MoreShanghai Yuantai Chemical Products Co., Ltd
Contact:021--66129803
Address:Chengyin Road,Shanghai,China
Nanjing Samwon International Limited
Contact:+86-25-84873444
Address:1108, BLDG B, New Century Plaza, No 1, South Taiping Rd.,
Taizhou Chemedir Biopharm-tech Co., Ltd
Contact:+86 523 86200218
Address:G09, No. 1 Avenue China Medical City, Taizhou,Jiangsu, China
Hefei EnliPharma Tecnology Co.,Ltd
Contact:0086-551-66399836
Address:Qing Cheng ShuiXiang Building 805, Mengcheng North Road , ShuangFeng Economic Development Zone Anhui HeFei
A.M FOOD CHEMICAL CO., LIMITED
Contact:86-531-87100375
Address:20Floor，Bblock，1Building，pharma-valley，Jinan，China
Doi:10.1021/ja017613b
(2002)Doi:10.1002/1522-2675(200204)85:4<1102::AID-HLCA1102>3.0.CO;2-T
(2002)Doi:10.1016/S0022-328X(00)81437-0
(1977)Doi:10.1055/s-1977-24441
(1977)Doi:10.1016/0584-8539(80)80077-8
(1980)Doi:10.1002/hlca.19770600613
(1977)
