Hypervalent iodine in synthesis XXXI: Formation of phosphinimines and arsinimines by nitrene route or non-nitrene route

Article abstract of DOI:10.1080/00397919908086232

N-sulfonyltriphenylphosphinimines and N-sulfonyltriphenylarsinimines are prepared by the reaction of triphenylphosphine or triphenylarsine under nitrene-producing conditions with I-N ylide (PhI=NSO₂R). Triphenylarsinimines can also be generated by a non-nitrene route from triphenylarsine, iodobenzene diacetate, and sulfonamides via triphenylarsine diacetate, Ph₃As(OAc)₂.

Full text of DOI:10.1080/00397919908086232

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Hypervalent Iodine in Synthesis
XXXI: Formation of Phosphinimines
and Arsinimines by Nitrene Route or
Non-Nitrene Route
Wei Ou a , Zhi-Gang Wang a & Zhen-Chu Chen a
a Department of Chemistry , Hangzhou University ,
Hangzhou, Zhejiang, 310028, P.R. China
Published online: 17 Sep 2007.
To cite this article: Wei Ou , Zhi-Gang Wang & Zhen-Chu Chen (1999) Hypervalent Iodine
in Synthesis XXXI: Formation of Phosphinimines and Arsinimines by Nitrene Route or Non-
Nitrene Route, Synthetic Communications: An International Journal for Rapid Communication
of Synthetic Organic Chemistry, 29:13, 2301-2309, DOI: 10.1080/00397919908086232
To link to this article: http://dx.doi.org/10.1080/00397919908086232
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