Novel unusually stable peroxotitanium(IV) compounds. Molecular and crystal structure of peroxobis(picolinato)(hexamethylphosphoric triamide)titanium(IV)

Article abstract of DOI:10.1021/ic00134a004

The synthesis, structure, and properties, with respect to oxygen transfer to various substrates, of peroxotitanium(IV) derivatives 1-5 are reported. The X-ray crystal structure of 1 essentially revealed that the O-O distance in the peroxo group is short a