Heterocycles p. 169 - 187 (2003)
Update date:2022-08-04
Topics: Total synthesis Intramolecular [4+2] Cycloaddition Securinine
Honda, Toshio
Namiki, Hidenori
Kudoh, Mika
Nagase, Hiromasa
Mizutani, Hirotake
An intramolecular Diels-Alder reaction of the enol ester derived from 2-acetylpyridine and sorbic anhydride gave the cycloaddition product, stereoselectively, which was further converted into the key intermediate for the synthesis of securinine.
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