A reinvestigation of the Beckmann rearrangement of (-)-menthone oxime: Preparation of (+)-(3S,6R)-3-isopropyl-6-methylhexahydroazepin-2-one

Article abstract of DOI:10.1080/00397919208021303

The titled compound was prepared by the Beckmann rearrangement of (-)-menthone oxime in polyphosphoric acid, and the value of its optical rotation was revised.

Full text of DOI:10.1080/00397919208021303

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Synthetic Communications: An
International Journal for Rapid
Communication of Synthetic
Organic Chemistry
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A Reinvestigation of the
Beckmann Rearrangement
of (-)-Menthone Oxime:
Preparation of (+)-
(3S,6R)-3-Isopropyl-6-
methylhexahydroazepin-2-one
Naoki Komatsu a , Satosi Simizu a & Toshio Sugita a
a Department of Hydrocarbon Chemistry, Faculty of
Engineering , Kyoto University , Sakyo-ku, Kyoto,
606-01, Japan
Published online: 23 Sep 2006.
To cite this article: Naoki Komatsu , Satosi Simizu & Toshio Sugita (1992)
A Reinvestigation of the Beckmann Rearrangement of (-)-Menthone Oxime:
Preparation of (+)-(3S,6R)-3-Isopropyl-6-methylhexahydroazepin-2-one, Synthetic
Communications: An International Journal for Rapid Communication of Synthetic
Organic Chemistry, 22:2, 277-279
To link to this article: http://dx.doi.org/10.1080/00397919208021303
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