Journal of the American Chemical Society p. 3740 - 3742 (1989)
Update date:2022-08-04
Topics:
Poulter, C. Dale
Muehlbacher, Manfred
Davis, Darrell R.
Isopentenyldiphosphate:dimethylallyldiphosphate isomerase catalyzes an antarafacial <1.3> proton migration by an electrophilic addition-elimination mechanism.Incubation of yeast isomerase with 3-(fluoromethyl)-3-butenyl diphosphate (3) led to rapid inacti
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