Isopentenyldiphosphate Isomerase. Machanism of Active-Site-Directed Irreversible Inhibition by 3-(Fluoromethyl)-3-butenyl Diphosphate

DOI: 10.1021/ja00192a037

Source and publish data:

Journal of the American Chemical Society p. 3740 - 3742 (1989)

Update date:2022-08-04

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Authors:

Poulter, C. Dale

Muehlbacher, Manfred

Davis, Darrell R.

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Article abstract of DOI:10.1021/ja00192a037

Isopentenyldiphosphate:dimethylallyldiphosphate isomerase catalyzes an antarafacial <1.3> proton migration by an electrophilic addition-elimination mechanism.Incubation of yeast isomerase with 3-(fluoromethyl)-3-butenyl diphosphate (3) led to rapid inacti

Full text of DOI:10.1021/ja00192a037

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