Tetrahedron p. 2507 - 2514 (1992)
Update date:2022-09-26
Topics:
Saeed, Ashraf
Young, Douglas W.
The enzyme serine hydroxymethyltransferase (EC 2.1.2.1) has been used in the synthetic direction with a variety of aldehyde substrates to form carbon---carbon bonds with the creation of two chiral centres. A variety of β-hydroxyaminoacids has been prepared in reasonable yields but, although L-stereo specificity is observed at the α-centre, stereospecificity is not high at the β-centre when the reaction is conducted on the preparative scale.
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(1968)
