Trichloroacetic Acid in Dimethyl Sulphoxide as a Source of Trichloromethyl Anions: Formation of an Adduct and Substitution Product with 1,3,5-Trinitrobenzene

DOI: 10.1039/c39830000140

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 140 - 141 (1983)

Update date:2022-08-03

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Authors:

Atkins, Paul J.

Gold, Victor

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Article abstract of DOI:10.1039/c39830000140

Solutions of trichloroacetic acid in dimethyl sulphoxide generate trichloromethyl anions which can be trapped by species susceptible to nucleophilic attack, such as 1,3,5-trinitrobenzene; the procedure is preparatively useful.

Full text of DOI:10.1039/c39830000140

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