Heterocyclic Communications p. 375 - 378 (2005)
Update date:2022-08-04
Topics:
Desalegn, Nebiyou
Vasquez, Pedro C.
Franklin, Paul J.
Kennedy, G. Davon
Baumstark
The thermal decomposition of trans-3-chloro-4,4,5-trimethyl-2,5-diphenyl-4, 5-dihydro-3H-pyrazole (1) produced 1,1,3-trimethyl-2-phenylindene (2) in excellent yield. A kinetic analysis showed that the reaction involved isolable diene intermediate(s) and yielded activation parameters for thermolysis of 1 of: ΔH?= 32.9 kcal/mole; ΔS?= -2.4 eu; ΔG?= 33.9 kcal/mole; k1, (180°C) - 1.3×10-3s -1.
Hubei Xiangxi Chemical Industry Co.,Ltd
Contact:+86-710-3454830
Address:No.7, Daqing East Road, Xiangfan City, Hubei Province, China
jiangsu hualin chemical co.,ltd.
Contact:86-25-87787402
Address:jaingsu,china
Contact:+1-973-357-0577
Address:10 Taft Rd.
Buffett (China) Holding Co.,Ltd
Contact:4006570891
Address:
Contact:86-931-8272767
Address:Room 602, No.461, Nanchang Road, Chengguan District, Lanzhou City, China PRC
Doi:10.1002/ardp.19733061105
(1973)Doi:10.1007/BF00909646
(1973)Doi:10.1016/j.bmc.2018.10.020
(2018)Doi:10.1039/jr9580002995
(1958)Doi:10.1021/acs.orglett.0c01701
(2020)Doi:10.1021/jm00247a012
(1974)
