DIMETHYLALUMINIUM HALIDE INDUCED REACTIONS OF FORMALDEHYDE WITH ALKYNES. SYNTHESIS OF α-ALLENIC ALCOHOLS AND Z-3-CHLOROALLYLIC ALCOHOLS

DOI: 10.1016/0040-4039(80)80199-7

Source and publish data:

Tetrahedron Letters p. 3857 - 3860 (1980)

Update date:2022-09-26

Topics:

Authors:

Rodini, David J.

Snider, Barry B.

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Article abstract of DOI:10.1016/0040-4039(80)80199-7

The CH2O.Me2AlCl complex reacts with terminal alkynes to give α-allenic alcohols via a formal ene reaction and Z-3-chloroallylic alcohols via a stereospecifically syn Fridel-Crafts addition.

Full text of DOI:10.1016/0040-4039(80)80199-7

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