Journal of Organic Chemistry p. 2158 - 2165 (1985)
Update date:2022-08-05
Topics:
Thea, Sergio
Cevasco, Giorgio
Guanti, Giuseppe
Hopkins, Andrew
Kashefi-Naini, Nasrin
Williams, Andrew
The alkaline hydrolysis of o- and p-hydroxyarenesulfonate esters of acidic phenols proceeds via an E1cB mechanism.Sulfoquinone (IUPAC name thioquinone dioxide) intermediates (e.g., 8) constitute the best hypothesis to account for the observed kinetic results which obey the rate law kobsd (hydrolysis) = (ka + kb
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