COMPETITIVE DIRADICAL AND DIAZOALKANE FORMATION IN THE THERMOLYSIS AND PHOTOLYSIS OF THE AZOALKANE 7,7,8-TRIMETHYL-2,3-DIAZATRICYCLO4,8>NON-2-ENE

DOI: 10.1016/S0040-4039(00)81748-7

Source and publish data:

Tetrahedron Letters p. 1699 - 1702 (1983)

Update date:2022-08-04

Topics:

Authors:

Adam, Waldemar

Gillaspey, William D.

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Article abstract of DOI:10.1016/S0040-4039(00)81748-7

On laser photolysis of azoalkane 1 at elevated temperature, besides the expected denitrogenation into the tricyclane 3 via 1,3-diradical 2, the diazolkane 7 is directly observed, denitrogenating into vinylcyclopentene 5.

Full text of DOI:10.1016/S0040-4039(00)81748-7

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