COMPETITIVE DIRADICAL AND DIAZOALKANE FORMATION IN THE THERMOLYSIS AND PHOTOLYSIS OF THE AZOALKANE 7,7,8-TRIMETHYL-2,3-DIAZATRICYCLO4,8>NON-2-ENE

DOI: 10.1016/S0040-4039(00)81748-7

Source and publish data:

Tetrahedron Letters p. 1699 - 1702 (1983)

Update date:2022-08-04

Topics:

Authors:

Adam, Waldemar

Gillaspey, William D.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)81748-7

On laser photolysis of azoalkane 1 at elevated temperature, besides the expected denitrogenation into the tricyclane 3 via 1,3-diradical 2, the diazolkane 7 is directly observed, denitrogenating into vinylcyclopentene 5.

Full text of DOI:10.1016/S0040-4039(00)81748-7

Products guided by the article

Product name:Cyclopentene, 4-(2-methoxyethyl)-1,5,5-trimethyl-

Cas No:52557-78-5

R&D Labs maybe for 52557-78-5

Brichem ( Haikou ) Co. Ltd.

Contact:86-898-65311214

Address:Room 102, BLDG. 68 Jiangnan City, No. 66 Heping Road,Haikou, Hainan, China
Tianjin Emulsion Science&Technology Development Co.,Ltd

Contact:13901380442

Address:Vake Garden New Town New Yi Bai Road Beichen District Tianjin,China
Xi'an Tizan Tech & Industry Co., Ltd.

Contact:86-18629066522

Address:C3009 TANG FENG INTERNATIONAL PLAZA, NO.18 FENGHUI NAN ROAD, XI'AN HIGH TECH ZONE, 710075 CHINA.
Foreschem Co., Ltd

Contact:+86-533-3112891

Address:zibo
Wuhan Sunrise Pharmaceutical Technology Co., Ltd

Contact:+86-27-83314682

Address:Room 340, New material Industrial base No.17, Gu Tian Five Lu , Qiaokou District, Wuhan , China

Relevant to this article

Peroxidation of S-(2-Methyl-2-propyl) 2-Methyl-2-propanesulfinothioate

Doi:10.1021/jo00241a025
(1988)
An intramolecular case of sharpless kinetic resolution: Total synthesis of laulimalide

Doi:10.1002/1521-3773(20011015)40:20<3842::AID-ANIE3842>3.0.CO;2-R
(2001)
Novel and selective 5-HT(2C/2B) receptor antagonists as potential anxiolytic agents: Synthesis, quantitative structure - Activity relationships, and molecular modeling of substituted 1-(3- pyridylcarbamoyl)indolines

Doi:10.1021/jm970741j
(1998)
Palladium-catalyzed carbonylative cyclization of unsaturated aryl iodides and dienyl triflates, iodides, and bromides to indanones and 2-cyclopentenones

Doi:10.1021/ja0212009
(2003)
DI-2-PYRIDYL SULFITE. A NEW USEFUL REAGENT FOR THE PREPARATION OF N-SULFINYLAMINES, NITRILES, ISOCYANIDES, AND CARBODIIMIDES UNDER MILD CONDITIONS

Doi:10.1016/S0040-4039(00)84413-5
(1986)
Design and structure-activity relationships of 2-alkyl-3-aminomethyl-6-(3-methoxyphenyl)-7-methyl-8-(2-fluorobenzyl) imidazolo[1,2-α]pyrimid-5-ones as potent GnRH receptor antagonists

Doi:10.1021/jm0205402
(2003)

Article Doi