Peroxidation of S-(2-Methyl-2-propyl) 2-Methyl-2-propanesulfinothioate

DOI: 10.1021/jo00241a025

Source and publish data:

Journal of Organic Chemistry p. 1263 - 1266 (1988)

Update date:2022-08-04

Topics:

Authors:

Freeman, Fillmore

Lee, Choonsun

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00241a025

Oxidation of 1 equiv of S-(2-methyl-2-propyl) 2-methyl-2-propanesulfinothioate (1) with 2 equiv of m-chloroperoxybenzoic acid (MCPBA) gives S-(2-methyl-2-propyl) 2-methyl-2-propanesulfonothioate (4, 13percent), 2-methyl-2-propanesulfenic 2-methyl-2-propanesolfonic thioanhydride (5, 32percent), 2-methyl-2-propyl-3-chlorobenzoate (11, 4percent), 2-methyl-2-propyl 2-methyl-2-propanesulfinate (12, 22percent), and small amounts of bis(2-methyl-2-propyl) trisulfide (7) and bis(2-methyl-2-propyl) tetrasulfide (10).Possible mechanisms for product formation are discussed.

Full text of DOI:10.1021/jo00241a025

Products guided by the article

Product name:2-methyl-2-propanesulfenic 2-methyl-2-propanesulfonic thioanhydride

Cas No:52754-01-5

R&D Labs maybe for 52754-01-5

Shijiazhuang Haitian Amino Acid Co., Ltd.

Contact:+86-311-88908111

Address:Shijiazhuang Hebei province,China
Shenzhen Sunrising Industry Co., ltd.

Contact:+86 755 86571158 / 86571159 / 86571160

Address:2108 ZHENYE INT. BUSINESS CENTER,NO.3101-90 QIANHAI RD, NANSHAN,SHENZHEN, CHINA
Shandong Topscience Biotech Co., Ltd.

Contact:0633-2619278

Address:No. 98 Lanshan West Road, Lanshan District, Rizhao, Shandong Province, P.R. of China
Chengdu Biopurify Phytochemicals Ltd.

website:http://www.phytopurify.com

Contact:+86-28-82633397

Address:2F,No.11 Building,No.388 Rongtaidadao CNSTP,Wenjiang Zone,Chengdu,Sichuan, China
ShanDong XinDa Chemical CO.,LTD(expird)

Contact:086-0311-87580543

Address:No.168, High Technology Development Zone Jinan Shandong China

Relevant to this article

DI-2-PYRIDYL SULFITE. A NEW USEFUL REAGENT FOR THE PREPARATION OF N-SULFINYLAMINES, NITRILES, ISOCYANIDES, AND CARBODIIMIDES UNDER MILD CONDITIONS

Doi:10.1016/S0040-4039(00)84413-5
(1986)
Design and structure-activity relationships of 2-alkyl-3-aminomethyl-6-(3-methoxyphenyl)-7-methyl-8-(2-fluorobenzyl) imidazolo[1,2-α]pyrimid-5-ones as potent GnRH receptor antagonists

Doi:10.1021/jm0205402
(2003)
In situ generation of nitroso compounds from catalytic hydrogen peroxide oxidation of primary aromatic amines and their one-pot use in hetero-Diels-Alder reactions

Doi:10.1002/ejoc.200700368
(2007)
Macrocyclic ligands with partially fluorinated sidearms: Synthesis and metal ion complexation

Doi:10.1016/S0040-4020(00)00248-9
(2000)
Palladium-Catalyzed Sequential C-H Activation/Amination with Diaziridinone: An Approach to Indoles

Doi:10.1021/acs.orglett.1c01043
(2021)
Chiral protic imidazolium salts with a (-)-menthol fragment in the cation: Synthesis, properties and use in the Diels-Alder reaction

Doi:10.1039/c7ra12176h
(2018)

Article Doi