Tetrahedron Letters p. 827 - 830 (1980)
Update date:2022-08-04
Topics:
Wolfe, Saul
Schirlin, Daniel
Dibenzyl disulfide is deprotonated at -78° approximately 7.5 times more rapidly than dibenzyl sulfide, as predicted by a molecular orbital analysis which focuses on the interaction between the carbon lone pair and an adjacent σ * orbital.
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