Journal of the Chemical Society. Chemical communications p. 214 - 216 (1983)
Update date:2022-09-26
Topics:
Bleasdale, Christine
Jones, David W.
Contrary to an earlier claim, reactions of (1) with m-chloroperbenzoic acid, N-bromosuccinimide, and N-chlorosuccinimide give the diester (15) and the syn-norbornadienes (2), (4), and (6), respectively; reactions of (1) with lead tetra-acetate and iodine also proceed with retention of C-7 stereochemistry but with bromine and chlorine inversion at C-7 is increasingly dominant.
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