Tetrahedron p. 2737 - 2742 (1978)
Update date:2022-08-04
Topics:
Boehmer, Volker
Woersdoerfer, Klasu
Becher, Ulrike
The kinetics of the aminolysis of different nitrophenylacetates were investigated with n-butylamine in dioxane at 20°C. The reaction rate can be described up to high concentrations of amine (~1 mole dm-3) by the equation v=k2[ester][amine]+k3[ester][amine]2. The ratio k3 k2 is larger for p-nitrophenylacetates than for o-nitrophenylacetates, while for 2,4-dinitrophenylacetates a third order term is not observed.
Contact:+86+21-58956006 15800617331
Address:402 Room, 150# Cailun Road, Zhangjiang high tech park, Shanghai
Contact:+8613400661290
Address:No 908,Kangwan Rd, Liuyang Economic
Nanjing Qirui Material Co., Ltd.
Contact:+86-25-52320053
Address:F4-5, #17 Building, Chuang Yi Yuan, No.6 Guanghua East Street, Nanjing, 210007 P.R.China
Chengdu Green Young Biopharmaceutical INC
Contact:+86-28-85337952
Address:1-B-26,Tianhe Industry Park, No.1480 of Tianfu Road,Chengdu,P.R.China,610000
Jiangsu Fengshan Group Co., Ltd.
Contact:86-25-86558671
Address:1903,Central International Mansion 105-6 North Zhongshan Road, Nanjing, China
Doi:10.1021/jm060315a
(2006)Doi:10.1021/ol0614471
(2006)Doi:10.1021/ol101993q
(2010)Doi:10.1246/bcsj.57.1138
(1984)Doi:10.1021/ja0625834
(2006)Doi:10.1016/j.bmc.2006.05.077
(2006)
