Tetrahedron p. 2737 - 2742 (1978)
Update date:2022-08-04
Topics:
Boehmer, Volker
Woersdoerfer, Klasu
Becher, Ulrike
The kinetics of the aminolysis of different nitrophenylacetates were investigated with n-butylamine in dioxane at 20°C. The reaction rate can be described up to high concentrations of amine (~1 mole dm-3) by the equation v=k2[ester][amine]+k3[ester][amine]2. The ratio k3 k2 is larger for p-nitrophenylacetates than for o-nitrophenylacetates, while for 2,4-dinitrophenylacetates a third order term is not observed.
Anhui Dexinjia Biopharm Co., Ltd
Contact:+86-531-82375818
Address:9 Hexie Road, kaifaqu, Taihe
Shanghai Massive Chemical Technology Co., Ltd.
website:http://www.massivechem.com/
Contact:+86 21 34943721
Address:Room 435, 4th floor, Building 9, No. 2568 Gudai Road,Minhang District, Shanghai,
Jiangsu Chiatai Qingjiang Pharmaceutical Co.,Ltd
Contact:+86-517-86283327
Address:9 North Hantai Road, Huaian, China
Contact:+86-29-88710656
Address:South Tai bai Road, High Tech Development Zone, Xi'an China
Contact:+86-25-83719363
Address:106-7 Chunnan Rd, Chunxi Town, Gaochun, Nanjing, China
Doi:10.1021/jm060315a
(2006)Doi:10.1021/ol0614471
(2006)Doi:10.1021/ol101993q
(2010)Doi:10.1246/bcsj.57.1138
(1984)Doi:10.1021/ja0625834
(2006)Doi:10.1016/j.bmc.2006.05.077
(2006)
