Chemistry Letters p. 1 - 4 (1982)
Update date:2022-09-26
Topics:
Maruyama, Kazuhiro
Otsuki, Tetsuo
Osuka, Atsuhiro
Suzuki, Hitomi
The oxirane ring of epoxynaphthoquinones was reductively opened upon irradiation in the presence of triethylamine and, in addition, a cross adduct was obtained in the reaction with N,N-dimethylaniline in benzene.CIDNP signals observed in the reaction with N,N-dimethylaniline were interpreted as evidence for hydrogen atom abstraction in benzene and for electron transfer in acetone and acetonitrile.
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