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vinylsulfones through a highly selective iodosulfonylation of
allenes in the presence of CuI and 1,10-phen in moderate to
excellent yields under mild conditions. These reactions
underwent very rapidly and tolerated diverse functionalities
on various readily available starting materials. Furthermore,
preliminary application exploration disclosed that the resulting
α,β-unsaturated allylic iodide derivatives are useful synthons
for the synthesis of multifunctional vinylsulfones.
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ASSOCIATED CONTENT
* Supporting Information
The Supporting Information is available free of charge on the
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S
Screening of reaction conditions, experimental proce-
dures, X-ray diffraction data, and H and 13C NMR
1
spectra of all compounds (PDF)
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Accession Codes
CCDC 1846775 contains the supplementary crystallographic
data for this paper. These data can be obtained free of charge
bridge Crystallographic Data Centre, 12 Union Road,
Cambridge CB2 1EZ, UK; fax: +44 1223 336033.
AUTHOR INFORMATION
Corresponding Authors
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ORCID
(21) Nakao, Y.; Shirakawa, E.; Tsuchimoto, T.; Hiyama, T. J.
Organomet. Chem. 2004, 689, 3701.
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Notes
The authors declare no competing financial interest.
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ACKNOWLEDGMENTS
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We thank the NSFC (U1604285, 21772032 and 21702051),
PCSIRT (IRT1061), the 111 Project (D17007), Science &
Technology Innovation Talents in Universities of Henan
Province (17HASTIT002), and Outstanding Young Talent
Cultivation Project Funding of Henan Normal University
(14YR002).
̈
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