PhLi-initiated cycloisomerization of unsaturated organoiodides: Mechanism of the isomerization of olefinic primary alkyl iodides

DOI: 10.1016/S0040-4039(99)01067-9

Source and publish data:

Tetrahedron Letters p. 5433 - 5437 (1999)

Update date:2022-08-04

Topics:

Authors:

Bailey, William F.

Carson, Matthew W.

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Article abstract of DOI:10.1016/S0040-4039(99)01067-9

Evidence is presented indicating that the PhLi-initiated cycloisomerization of olefinic primary alkyl iodides involves a radical- mediated atom transfer process that had previously been implicated in the isomerization of secondary and tertiary substrates.

Full text of DOI:10.1016/S0040-4039(99)01067-9

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